Troopers responded to the crash around 4:10 am.
They said Harold Durand, 54, of Pollock ran the stop sign and was struck by the rig driven by Joseph Winford, 29, of DeRidder.
Winford was killed on impact; Durand died later at an Alexandria hospital.
Hazmat personnel were called out to clear the roadway of the primary east-west artery across Central Louisiana.
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